Product ID:ST-96 ACC40195, ST96100
MSDS Date:04/12/1991
FSC:6810
NIIN:00N026254
MSDS Number: BMRPD

FISHER SCIENTIFIC CHEMICAL DIV

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

THE CORNEA & 300 PPM FOR 6 HRS SHOWED SLIGHT EROSION

RTECS: 9999999ZZ

CAUSE FROSTBITE. (CHRONIC)ANIMALS EXPSD TO VAP AT

RTECS: 9999999ZZ

UNREST & IRRIT OF EYES, BUT NO OCULAR INJURY.EFTS

RTECS: 9999999ZZ

SIMILAR TO THOSE FOR ACUTE EXPOS MAY OCCUR.

RTECS: 9999999ZZ

MOUTH, THROAT, ESOPHAGUS & STOMACH W/CONSEQUENT

RTECS: 9999999ZZ

SHOCK & INTENSE THIRST. NEPHRITIS, FEVER &

RTECS: 9999999ZZ

OCCUR.DEATH MAY BE DUE TO ESOPHAGEAL/GASTRIC

RTECS: 9999999ZZ

FROM AS FAR A DISTANCE AS POSSIBLE. AVOID

RTECS: 9999999ZZ

CA HYPOCHLORITE,CS ACETYLINE, CL +

RTECS: 9999999ZZ

DOWICIL 100,ETHYLENE DIAMINE,ETHYLENE

RTECS: 9999999ZZ

METAL ACETYLIDES, METALS, OLEUM, OXIDIZERS,

RTECS: 9999999ZZ

PERMANGANATE, BETA-PROPIOLACTONE,PROPYLENE

RTECS: 9999999ZZ

TETRANITRIDE AND VINYL ACETATE.

RTECS: 9999999ZZ

HYDROCHLORIC ACID; (HYDROGEN CHLORIDE)

CAS: 7647-01-0

RTECS: MW4025000

Fraction By Weight: 3.2%

OSHA PEL 5 PPM, C

ACGIH TLV: 5 PPM, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TITANIUM (METAL)

CAS: 7440-32-6

RTECS: XR1700000

Fraction By Weight: 0.09%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 96.71%

EXPOS. REPRO EFTS HAVE BEEN RPTD IN

RTECS: 9999999ZZ

DISCOLORATION OF EXPSD TEETH, CHRONIC BRONCH &

RTECS: 9999999ZZ

IRRIT, INFLAM, ULCERATION, NECROSIS & CHEM

RTECS: 9999999ZZ

COLLAPSE, PHOTOSENSIT RXN MAY OCCUR IN PERSONS

RTECS: 9999999ZZ

(CHRONIC)RPTD/PRLNGD CONT W/VAPS/DILUTE SOLN MAY

RTECS: 9999999ZZ

(ACUTE)CONT MAY CAUSE SEVERE IRRIT, CONJ, CORNEAL

RTECS: 9999999ZZ

A DROP OF HYDROCHLORIC ACID SPLASHED IN EYE & IMMED

RTECS: 9999999ZZ

CORNEAL & CONJUNCTIVAL EPITHELIUM.ANIMALS EXPSD TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:(ING 1)CORR. 100 PPM IMMED
DANGEROUS TO LIFE/HLTH.(ACUTE)INHAL OF GAS/FUMES AT LEVS OF 5-35
PPM MAY CAUSE IRRIT & BURNING OF THROAT, COUGHING & CHOKING; 50-100
PPM MAY BE BARELY TOLERABLE FOR 1 HR.HIGH LEVS MAY CAUSE INFLAM &
OCCASNLY ULCERATION OF NOSE, THROAT/LARYNX, BRONCH, PNEUM,
PALPITATIONS(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:& HDCH. HIGHER CONC MAY CAUSE NECROSIS
OF TRACHEAL & BRONCHIAL EPITHELIUM, NASOSEPTAL PERFORATION,
ATELECTASIS, EMPHYSEMA, DMG TO PULM BLOOD VESSELS & LESIONS OF
LIVER & OTHER ORGANS. DEATH M AY BE DUE TO LARYNGEAL SPASM,
BRONCHOPNEUMONIA/PULM EDEMA. 1300-2000 PPM MAY BE DANGEROUS, EVEN
ON BRIEF (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) . EYES:
IMMEDIATELY FLUSH EYES WITH POTABLE WATER FOR A MINIMUM OF 15
MINUTES, SEEK ASSISTANCE FROM MD . SKIN: FLUSH WITH COPIOUS
AMOUNTS OF WATER. CALL MD . FOR SPECIFIC FIRST AID PROCEDURES SEE
ORIGINAL MSDS .

Extinguishing Media:DRY CHEMICAL, CO*2, WATER SPRAY OR REGULAR FOAM.
FOR LRG FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/O RISK.APPLY COOLING
WATER TO SIDES OF CNTNRS THAT (SUPP DATA)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:COVER WITH SODA ASH. SCOOP UP AND PLACE IN A
SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:THE SPECIFIC NIOSH/MSHA APPRVD RESP MUST BE
BASED ON CONTAM LEVS FOUND IN WORK PLACE. FOR FURTHER INFORMATION
SEE ORIGINAL MSDS .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:PROTECTIVE GLOVES.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD
Other Protective Equipment:APPROPRIATE PROT (IMPERVIOUS) CLOTHING AND
EQUIP. EYE WASH FOUNTAIN AND QUICK DRENCH SHOWER. DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:ARE EXPSD TO FLAMES UNTIL WELL AFTER FIRE IS OUT.STAY
AWAY FROM ENDS OF TANKS.EXTING USING AGENTS INDICATED;DO NOT USE
WATER DIRECTLY ON MATL.IF LRG AMTS OF COMBUST MATLS ARE INVOLVED,
USE WATER SPRAY/FOG IN FLOODING AMTS.USE WATER SPRAY TO ABSORB CORR
VAPS.COOL CNTNRS W/FLOODING AMTS OF WATER (ING 19)

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:14
Vapor Density:0.7
Spec Gravity:1.0
Evaporation Rate & Reference:>1 (ETHER = 1)
Solubility in Water:COMPLETELY
Appearance and Odor:REDDISH-ORANGE LIQUID.

Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDRIDE, ALCOHOLIC CYANIDE, AL,AL-TITANIUM
ALLOYS,2-AMINOETHANOL, NH*4OH,BASES,BRASS,BRONZE,CA CARBIDE(ING 20)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
CORROSIVE HYDROGEN CHLORIDE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE & LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.